Introduction
Radiocarbon dating and calibrating the obtained date into calendar years is a crucial step in understanding the timing and chronology of past events. Archaeologist An archaeologist is responsible in for deciding which sample dates the event they want to date; they are also responsible in for taking the sample and filling in the requested sampling reports for the collections and each . Each laboratory preforming performing the radiocarbon dating service needs them to fill in a specific sample list (online or sent via email).
References
A short guide about radiocarbon dating in archaeology for archaeologists can be found here:https://www.archemy.ee/methods-in-a-nutshell/.
https://historicengland.org.uk/images-books/publications/radiocarbon-dating-chronological-modelling/radiocarbon-dating/#s17Conventions on reporting dates: Millard AR. Conventions for Reporting Radiocarbon Determinations. Radiocarbon. 2014;56(2):555-559. doi:10.2458/56.17455
Sample Selection
This step affects the reliable application of radiocarbon dating the most (Becerra-Valdivia & Higham 2023, 26). Thus, as an archaeologist it is crucial to ask the following questions while selecting the samples.
Chemical preparation of the sample
Data Acquisition
The radiocarbonlabgivesyouthefollowingrawdata: i) radiocarbondate in years BP (Before Present) and ii) uncertainty, thatisthe standard deviationoruncertaintyassociatedwiththeradiocarbondate, iii) labidentifier, for organicmaterialsalso iv) d13C valuewillbeprovided (measuredwith AMS), and forboneyou need tospecificallyaskforv) d13C and d15N valuesmeasuredwith EA-IRMS.
Tocalibratetheradiocarbondatesthere are several programmes available:
- OxCaldeveloped by the Oxford Radiocarbon Accelerator Unit:https://c14.arch.ox.ac.uk/oxcal.html
- BCal, developed and hosted by the School of Mathematical and PhysicalSciences at the University of Sheffield: https://bcal.shef.ac.uk/
- ChronoModelisanopen-sourceapplicationdeveloped at CNRS: https://chronomodel.com/
- R-packagesallowingcalibration of radiocarbondateslikercarbon:https://github.com/ahb108/rcarbon and
OxCal Scripts and Data Analysis Tools
SinceOxCalisfarthemostusedprogram, either online orvia a standaloneversion, tocalibratetheradiocarbondates, wewillbrieflydescribeitsworkflowhere.
Inputdata:usetheR_Date() functiontoinputtheradiocarbondate and itsuncertainty
-> Selectcalibrationcurve:choosetheappropriatecalibrationcurve (e.g., IntCal20 for Northern Hemisphereterrestrialsamples) -> Runcalibration:executethecalibrationprocesstoconverttheradiocarbondateinto a calendardate range (BCE/CEor AD) -> theprogramwillgenerate a probabilitydistribution of thecalibrateddate -> reviewresults:Analysetheoutput, whichincludesthecalibrateddate range and probabilitydistribution -> interprettheresults in thecontext of yourresearchquestion.
Detaileddescriptionsaboutvariousscripts are available in theOxCal online manual: https://c14.arch.ox.ac.uk/oxcalhelp/hlp_contents.html
Data reliability/limitation of method
Major challenges that affect the reliability of radiocarbon dates and their calibration into calendar years cab ne can be summed up as followingfollows:
- Fluctuations in atmospheric carbon-14. The concentration of carbon-14 in the atmosphere has varied over time due to factors like solar activity and geomagnetic field changes. These fluctuations require calibration using dendrochronology (tree rings) and other methods.
- Calibration curves. Building accurate calibration curves is a complex and time-consuming process. It involves thousands of radiocarbon dates and specialized
- specialised knowledge in dendrochronology.The curves can be “wiggly”, reflecting periods of higher or lower carbon-14 production rather than a steady state.
- Measurement precision. The precision of radiocarbon dating instruments can affect the accuracy of the results. Instrument limitations and sample preservation issues can lead to errors.
- Sample preservation. Poor preservation of samples can result in carbon loss, which affects the reliability of the radiocarbon date.
- Reservoir effects. Samples from marine environments or certain freshwater systems can have apparent ages that are older than their actual age due to the reservoir effect, where carbon-14 levels differ from those in the atmosphere.
- Contamination of samples with modern carbon can lead to inaccurate dates. Knowledge about the context of the sample, together with careful
- careful handling and preparation of samples are
- , is essential to avoid contamination.
Fig. Quality assurance of the ORAU.
References
Becerra-Valdivia, L. & Higham, T. 2023. New developments in Radiocarbon Dating. A. M. Pollard, R. A. Armitage, C. A. Makarevicz (eds), Handbook of Archaeological Sciences. 2nd Edition. John Wiley & Sons Ltd, 25–35.
Bone: Lanting, J.N., Aerts-Bijma, A.T. & van der Plicht, J. 2001. Dating of Cremated Bones. Radiocarbon, 43(2A), 249–254. https://doi.org/10.1017/S0033822200038078
DNA and 14C-dating: https://doi.org/10.1016/j.jas.2021.105452
Textiles:Margariti, C., Sava, G., Sava, T. et al. Radiocarbondating of archaeologicaltextiles at differentstates of preservation. HeritSci 11, 44 (2023). https://doi.org/10.1186/s40494-023-00867-x

